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>> people out in the general public say, oh, that's in russia. it's never going to happen here. but i know that it could happen here, too. i know that it can happen here because it happened to my husband. >> reporter: there's no proof the joyals are right, but paul's assailants have never been caught. and elizabeth joyal admits at first she was angry when he agreed to be interviewed again for this program. >> i said, what are you thinking? why do you want to bring notice once again? but then when the man in russia was shot, i had a kind of an epiphany. wait a minute. someone needs to talk abou...

>> seven months after the law was passed, someone was liquidated. a prominent russian journalist, shot in the head outside her moscow apartment. she was a friend of litvinenko. three weeks later, litvinenko himself was poisoned with polonium 210. duma leader zhirinovsky certainly didn't shed any tears when that happened but laughs off the notion that the russian state was connected in any way. for one simple reason. he thinks russian agents would have done a better job. >> translator: i'm surprised that the uk special services and the uk court accuses russia and lugovoi that with a bag of polo...

Conference room where he and litvinenko had met two weeks before the pine bar encounter. was anything spilled on the table? >> translator: richard, you are asking questions. i remember some things. i don't remember other things. i cannot answer these questions because these can be used against me in the court, which is done frequently. >> as for his last meeting with litvinenko at the pine bar, lugovoi says there's no way he brought polonium on that trip because his wife and children were with him. >> translator: a person's weakest spot is his family. and i'm a rational man. even if i had take...

Someone who was washing dishes in the pine bar or in a hotel, cleaning crew, do we know, ultimately? >> five months after litvinenko's death, scotland yard issued an arrest warrant for lugovoi. kovtun's would come later. the two responded with a press conference in moscow stating their innocence. [ speaking russian ] >> russia refused to extradite them, so we traveled to moscow to find the men who are wanted in connection with litvinenko's murder. coming up, the stakes get even higher as we confront a top russian official when "dateline" continues. saturdays happen.