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Terrified ukrainians running for their lives, seeking safety anywhere they can. the refugee agency saying more than 100,000 ukrainians are on the move since the invasion began more than 24 hours ago. in kharkiv, many residents seeking safety underground in the subway system. cnn's clarissa ward getting a firsthand look. c cha ris a? >> don, this time last night, the square behind ne the center of the city was lit up. the streets were quiet and tense but nothing like this. there is now a curfew in place, from 10:00 p.m. to 6:00 a.m., as people in this city brace themselves for what could come n...

City center in kyiv. it says russian reconnaissance troops have ended the northern district of the capitol and it's asking citizens to, quote, get this, make molotov cocktails and take down the occupier. it comes as ukraine's interior ministry says one of its fighter jets has been shot down over kyiv and as air raid sirens have, again, been going off around the capitol. now residents in kharkiv, ukraine, have turned a subway system into a make shift bomb shelter. clarissa ward was there speaking with frightened but determined ukrainians seeking safety. >> reporter: kharkiv residents scrambled ...

Kharkiv. clarissa ward is on the scene. you've been with innocent civilians who are so, so desperate to try to escape the violence. what are you seeing? >> reporter: that is right wolf. what a difference a day makes. last flight we were tanding out here and the square behind me was lit and it was tense, make no mistake about it. but there was nothing like the level of activity that we are now seeing today. there have been explosions, artillery trikes throughout the day. people here completely panicked, have you no idea where to go. fearing there could be an all-out assault on this city, ukrain...

Shelter. international correspondent clarissa ward was there and spoke with frightened but determined ukrainians seeking safety. >> reporter: kharkiv residents scrambled to find shelter as russia's brutal assault unfolds. deep underground, scenes reminiscent of the second world war. the shock just sinking in that what was unimaginable is now reality. as 36-year-old darya tells us. >> you wake up, and it's totally unreal. it's at 5:00 a.m., and you find out that the world is no longer the safe place you imagined. we are independent country, ukraine, and we are not same as russians. and we don't...

Yes, there was a deliberate, conscious choice by president putin to launch the war when we could still negotiate peace. kim? all right. thanks so much, jim bitterman in paris. and now, we want to go back to michael holmes in lviv. michael? >> yeah. thanks so much, kim, for picking it up. power went out here. it was nothing invasion related. it has been sorted out. let's go on, now. residents in kharkiv in ukraine -- they have turned to subway station into a makeshift-bomb shelter. cnn chief international correspondent clarissa ward was there, and spoke with frightened but determined ukrainia...