Abstract Sodium niobate (NaNbO )‐based dielectrics have received much attention for energy storage applications due to their low‐cost, lightweight, and nontoxic nature. The field‐induced metastable ferroelectric phase in NaNbO ‐based dielectrics, however, leads to a large hysteresis of the polarization–electric field (P–E) loops and hence deteriorate the energy storage performance. In this study, the hysteresis was successfully reduced by introducing Bi and Ti into A‐site and B‐site of NaNbO , respectively. MnO addition was added to further increase the ceramic density and ...