The crash happened near Ballyclare, on the Carrickfergus Road close to the Ballylagan Road, Ballynure, yesterday morning.
The incident was reported to police around 9.15am.
The male driver of the car was pronounced dead at the scene, while another patient was taken to Antrim Area Hospital by the Northern Ireland Ambulance Service (NIAS).
Officers remained at the scene yesterday conducting enquiries.
UUP councillor Vera McWilliam said her sympathies were with the loved ones and friends of the man who had died in the collision.
"This will be incredibly difficult news for them at what is only the start of 2021," she told the Belfast Telegraph.

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