Gucci wasn t a difficult choice for the Oscar nominee, whose husband of 14 years - François-Henri Pinault - literally owns the brand through his multinational corporation Kering
She was seen chatting up fired CNN personality Don Lemon, movie star Salma Hayek, talk show host Gayle King and model turned chef Padma Lakshmi. And she was cornered on the carpet.
The Frida actress brought her daughter Valentina, 15, and stepson Augustin, 16 - whose mother is Linda Evangelista - to the TIME 100 Gala, which took place at Jazz at Lincoln Center in New York City.