The optimal algorithm of Energy Storage System (ESS) has gained remarkable attention in developing a microgrid (MG) system to reduce the intensity of carbon emission in the electricity sector and alleviate the environmental impact by 2050. This article provides a historical background and a comprehensive analysis of the optimal algorithm of ESS in MG applications. A brief search has been directed through the Scopus database with some predefined conditions on the last week of January 2021 over 11 years to select the top-cited articles. This bibliometric study is evaluated in this field over the last decades based on the year of publication, interrelation of co- occurrence keywords, articles type, country of origin, journal, and publisher that published the 120 top-cited articles. A sum of 4995 articles was revealed within the year 2010 to 2020 in the field of the optimal algorithm of ESS in MG applications, and the top-most 120 papers were received in total 23003 citations (mean-119.69;
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