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"Regulating the Electronic Configuration of Supported Iron Nanoparticle" by Xiaowei Wang, Yanyan Zhao et al.

Electrocatalytic nitrogen reduction reaction (eNRR) is a sustainable alternative to the traditional Haber–Bosch process due to its eco-friendly nature and capability of utilizing renewable energy. However, its low Faradic efficiency (FE), caused by the excessive adsorption and reduction of protons, has been regarded as the main challenge, which leads to low ammonia yield as well. Herein, a carbon-supported iron electrocatalyst is reported, which is fabricated by low-temperature (300 °C) potas...
Carbon Based Electrocatalyst Electronic Configuration Fluorine Functionalization Ron Nanoparticle Nitrogen Fixation
Source: uow.edu.au

How metals work together to weaken hardy nitrogen-nitrogen bonds

Caption: MIT chemists have determined the structure of the complex that forms when gaseous dinitrogen, or N2, binds to an iron-sulfur cluster, offering clues as to how microbes (in yellow) use nitrogenases to break the nitrogen-nitrogen bond (in pink and green). *Terms of Use: Images for download on the MIT News office website are made available to non-commercial entities, press and the general public under a Creative Commons Attribution Non-Commer...
Daniel Suess Theodore Betley Alex Mcskimming Chemical Biology At Harvard University Department Of Chemistry Research Support Committee Fund
Source: mit.edu

"Strategic Structure Tuning of Yolk-Shell Microcages for Efficient Nitr" by Huinan Guo, Weiqin Li et al.

Abstract The electrocatalytic nitrogen reduction reaction (ENRR) under ambient conditions is considered as a promising process to produce ammonia. Towards highly efficient catalysts, here an optimized one-step pyrolysis strategy was tailored to design yolk–shell microcages (YS Co@C/BLCNTs), consisting of Co nanocrystals encapsulated in N-doped carbon framework and bridged by bamboo-like carbon nanotubes (BLCNTs). The cavity created between yolk and shell not only served as a “micro-bag” t...
N Doping Nitrogen Fixation Olk Shell
Source: uow.edu.au

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