Chinese Academy of Sciences
Recently, the research team led by Prof. KONG Lingtao from Institute of Solid State Physics, Hefei Institutes of Physical Science (HFIPS) prepared a highly active single iron atom catalyst (Fe-ISAs@CN) which can activate H
2O
2 to generate free radicals, achieving rapid removal of sulfadiazine pollutants in aqueous. The relevant results were published in Journal of Colloid and Interface Science.
Sulfadiazine (SDZ), a kind of synthetic sulfadiazine antibiotic, is widely used in clinical and animal husbandry industries. However, due to its large-scale use and unqualified discharge of wastewater, more and more antibiotic residues are detected in the water environment. These antibiotics are still highly toxic at very low concentrations. Due to the stable chemical structure of sulfadiazine, it is difficult to solve the residual problem with conventional processing technology.
People who eat too many refined carbs and fatty meats for dinner have a higher risk of heart disease than those who eat a similar diet for breakfast, according to a nationwide study published in the Endocrine Society s Journal of Clinical Endocrinology & Metabolism.
New MIT research confirms people visit places more frequently when they have to travel shorter distances to get there. The study establishes a “visitation law” and could help in urban planning.
Fossil seed-bearing structures preserved in a newly discovered Early Cretaceous silicified peat in Inner Mongolia, China, provide a partial answer to the origin of flowering plants, according to a study led by Prof. SHI Gongle from the Nanjing Institute of Geology and Paleontology of the Chinese Academy of Sciences (NIGPAS).
Abstract
Dehydrative cyclization of diols to O-heterocycles is attractive, but acid and/or metal-based catalysts are generally required. Here, we present a hydrogen-bond donor and acceptor cooperative catalysis strategy for the synthesis of O-heterocycles from diols in ionic liquids [ILs; e.g., 1-hydroxyethyl-3-methyl imidazolium trifluoromethanesulfonate ([HO-EtMIm][OTf])] under metal-free, acid-free, and mild conditions. [HO-EtMIm][OTf] is tolerant to a wide diol scope, shows performance even better than H
2SO
4, and affords a series of O-heterocycles including tetrahydrofurans, tetrahydropyrans, morpholines, dioxanes, and thioxane in high yields. Mechanism investigation indicates that the IL cation and anion serve as hydrogen-bond donor and acceptor, respectively, to activate the C─O and O─H bonds of alcohol via hydrogen bonds, which synergistically catalyze dehydrative cyclization of diols to O-heterocycles. Notably, the products could be spontaneously separated after reac