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Of course, but a tiny piece of material that appeared to have been torn from a rubber glove. so they requested a copy of daniel's walmart receipt. and what do you know -- the type of hair dye he bought came with a pair of gloves. oh, which did not match the snippet of blue material found at the crime scene. but daniel, it turned out, bought something else that morning at the walmart. a whole box of disposable gloves in blue nitrile. was that the same material as that tiny glove fragment found under shelley's wrist? why yes, it was. >> we were able to scientifically connect that little sliver o...

Could it be he really wanted the protective gloves that are generally included in a hair dye kit? >> gloves is important because there's evidence at the scene where a glove turned up. >> reporter: not a whole glove, of course, but a tiny piece of material that appeared to have been torn from a rubber glove. so they requested a copy of daniel's walmart receipt. and what do you know -- the type of hair dye he bought came with a pair of gloves. oh, which did not match the snippet of blue material found at the crime scene. but daniel, it turned out, bought something else that morning at the walmar...

Generally included in a hair dye kit? >> gloves is important because there's evidence at the scene where a glove turned up. >> reporter: not a whole glove, of course, but a tiny piece of material that appeared to have been torn from a rubber glove. so they requested a copy of daniel's walmart receipt. and what do you know -- the type of hair dye he bought came with a pair of gloves. oh, which did not match the snippet of blue material found at the crime scene. but daniel, it turned out, bought something else that morning at the walmart. a whole box of disposable gloves in blue nitrile. was tha...

Bought something else that morning at the walmart. a whole box of disposable gloves in blue nitrile. was that the same material as that tiny glove fragment found under shelley's wrist? why yes, it was. >> we were able to scientifically connect that little sliver of glove found at the scene as being of the same manufacturer and consistency of that glove that walmart sold on the day that daniel purchased those gloves. >> reporter: that was huge -- real evidence linking daniel to the crime scene. >> when all these facts comes together, there's no other suspect. and the reason that shelley was kil...

Where a glove turned up. >> reporter: not a whole glove, of course, but a tiny piece of material that appeared to have been torn from a rubber glove. so they requested a copy of daniel's walmart receipt. and what do you know -- the type of hair dye he bought came with a pair of gloves. oh, which did not match the snippet of blue material found at the crime scene. but daniel, it turned out, bought something else that morning at the walmart. a whole box of disposable gloves in blue nitrile. was that the same material as that tiny glove fragment found under shelley's wrist? why yes, it was. >> we...