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Optimizing Charge Separation in Heterojunctions for Water Splitting

Using photoelectrochemical (PEC) water splitting to produce green hydrogen from solar energy is a potentially practical approach. Unfortunately, the slow water oxidation reaction and very low charge separation efficiency of contemporary PEC systems make them unsuitable for practical applications. ....

Lun Pan , Skyla Baily , Green Energy Environment , School Of Chemical Engineering , Tianjin University , Charge Separation , Water Splitting , Formed Built In Electric Field , Polarized Induced Electric Field , Promote Carrier , Image Credit , Green Energy , Automation Industry Focus , Chemical Engineering , Study Lead , Corresponding Author ,

"Piezo-photoelectric all-in-one coaxial hierarchical TiO2-BaTiO3-CuInS2" by M. Yang, Y. Wang et al.

Rational multiple-field coupling, component control, and microarchitectures design for utilization of multiform driving forces as well as benefiting charge-carrier separation and migration is considered to be an outstanding approach to improve water splitting efficiency for alleviating increasing environmental problems. Herein, a novel piezo-photoelectric catalyst, coaxial TiO2-BaTiO3-CuInS2 heterostructures, was designed for efficient hydrogen production, synergistically driven by mechanical force, electricity, and light. The vertical growth of TiO2 nanorods guarantees sufficient generation of photoinduced charges and their fast migration. Electric field generated by the piezoelectric BaTiO3 shell under a mechanical driving force will promote the separation and transfer of photogenerated charge carriers, thereby minimizing the probability of charge recombination. The further incorporation of the outermost layer of CuInS2 is beneficial to broaden light harvesting. Of particular importa ....

Charge Separation , Oupling Effects , Piezoelectric Effect , Io Batio Cuins Hierarchical Heterojunction 2 3 ,

"Co-embedding oxygen vacancy and copper particles into titanium-based o" by Ge Yang, Jinyan Xiong et al.

Photocatalytic CO2 reduction into valuable fuel and chemical production has been regarded as a prospective strategy for tackling with the issues of the increasing of greenhouse gases and shortage of sustainable energy. A composite photocatalysis system employing a semiconductor enriched with oxygen vacancy and coupled with metallic cocatalyst can facilitate charge separation and transfer electrons. In this work, mesoporous TiO2 and titanium-based perovskite oxides (BaTiO3 and SrTiO3) nanoparticle assembly incorporated with abundant oxygen vacancy and copper particles have been successfully synthesized for CO2 photoreduction. As an example, the TiO2 decorated with different amounts of Cu particles has an impact on photocatalytic CO2 reduction into CH4 and CO. Particularly, the optimal TiO2/Cu-0.1 exhibits nearly 13.5 times higher CH4 yield (22.27 μmol g−1 h−1) than that of pristine TiO2 (1.65 μmol g−1 h−1). The as-obtained BaTiO3/Cu-0.1 and SrTiO3/Cu-0.1 also show enhanced CH4 ....

Charge Separation , O Photoreduction 2 , U Cocatalyst , Xygen Vacancy , Rio 2 , Itanium Perovskite Oxides ,

Red Magic 6S Pro With Snapdragon 888+ SoC, 165Hz Display Announced: Price, Specifications

Red Magic 6S Pro With Snapdragon 888+ SoC, 165Hz Display Announced: Price, Specifications
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