Magnesium phosphate cement (MPC) is one of the most promising binders to partially replace Portland cement to reduce carbon emissions. This study attempted to develop and design an ultra-high ductile MPC-based composite (UHDMC) using fly ash (FA) and silica fume (SF). Firstly, the macro-mechanical analysis of the UHDMC indicated that both the ultimate tensile stress and the ultimate tensile strain improved greatly when the additions of FA and SF replacing MPC were 30% and 20%, respectively. Compared to the addition of SF, the addition of FA resulted in a lower ultimate tensile stress but a hig...