"Enhanced corrosion protection of magnesium alloy via in situ Mg–Al LDH" by Pu Bo Li, Yong Xun Wang et al.
The Mg–Al layered double hydroxide (LDH) conversion coatings were first synthesized in situ to modify the AZ91D alloy through urea hydrolysis to adjust the pH values (9.4, 10.4, 11.2 and 11.4). The pH 11.2 Mg–Al LDH possessed the best compactness and good crystallinity compared to other in situ LDH coatings and obtained the lowest corrosion current density (icorr) of (2.884 × 10−6 ± 0.345 × 10−6) A·cm−2, which was attributed to the anion-exchange reaction of LDH and the physical barrier against corrosion owing to the twisted penetration pathway of the interlaced LDH sheets. Core...