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IMAGE: (a) Typical Reactivity Modes of -N2 Units in Transition Metal-Dinitrogen Complexes; (b) This Work: Catalytic Reactivity of Mo-N2 Units in the Disproportionation of Cyclohexadienes and Isomerization of Terminal Alkenes.
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Credit: ©Science China Press
Dinitrogen (N2) fixation is considered as one of the most essential tasks in basic science, providing straightforward methods to produce ammonia and nitrogen-containing molecules. Exploring the reactivity of N2 units of transition metal-nitrogen complexes is of great significance and challenging in the chemistry. Since the first Ru-N2 complex was prepared in 1965, important progress has been made in the synthesis and reactivity of transition metal nitrogen complexes. In many cases, terminal end-on M-N2 complexes as the most prevalent bonding mode were proved to be effective to catalyze reductive reactions of N2 to afford ammonia or silylamines; moreover, due to the nucleophilicity of d ....

Zhang Jie Shi , National Science Review , Fudan University , Professor Zhang Jie Shi , Chemistry Physics Materials Sciences , ஜாங் ஜிே ஷி , தேசிய அறிவியல் விமர்சனம் , ப்ரொஃபெஸர் ஜாங் ஜிே ஷி , வேதியியல் இயற்பியல் பொருட்கள் அறிவியல் ,