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For ethylene glycol. but we knew the only thing in those samples was propionic acid. >> when dr. shoemaker examined the graph shown to the jury during patricia stallings' trial, one showing the ethylene glycol found in ryan's blood, and next to it a graph of a known sample of ethylene glycol, he discovered a huge mistake. >> but the tragic thing is that no one bothered to actually superimpose the two like this. and when you look at it very closely and line up the injection point here and the internal standard here, the two peaks are actually quite different. and you move them up here so you ca...

>> there was a compound that was very highly elevated in the serum compound called propionic acid. it comes off very close but not identically with ethylene glycol. he and i speculated that that might be the basis of a misidentification that led to the incorrect diagnosis of ethylene glycol poisoning. >> propionic acid is often produced in patients who have mma, the rare genetic illness diagnosed in ryan's brother d.j. the only difference between propionic acid and ethylene glycol is a few carbon atoms. to find out if other labs were capable of misreading propionic acid as ethylene glycol, dr....

>> sure enough, three out of the seven laboratories we tested came back with positive results for ethylene glycol. but we knew the only thing in those samples was propionic acid. >> when dr. shoemaker examined the graph shown to the jury during patricia stallings' trial, one showing the ethylene glycol found in ryan's blood, and next to it a graph of a known sample of ethylene glycol, he discovered a huge mistake. >> but the tragic thing is that no one bothered to actually superimpose the two like this. and when you look at it very closely and line up the injection point here and the internal ...