"Multilayer asymmetric solid polymer electrolyte with modified interfac" by Qiang Lv, Yutong Jing et al.
Solid polymer electrolytes (SPEs) are promising for achieving safe solid-state Li metal batteries (SSLMBs). However, unstable electrode/electrolyte interface contact of SPEs limits their application at high voltage. To address this issue, we designed a multi-layer asymmetric SPE with a sandwich structure based on the hydroxyapatite (HAP) enhanced PVDF-HFP matrix. Two different interfacial modification layers were introduced on the anode and cathode sides. Methyl (2,2,2-trifluoromethyl) carbonate (FEMC) and tetramethylene sulfone (TMS) were selected as plasticizers in the layers, respectively, ...