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May 6, 2024
Optimizing the local electronic structure of electrocatalysts can effectively lower the energy barrier of electrochemical reactions, thus enhancing the electrocatalytic activity. However, the intrinsic contribution of the electronic effect is still experimentally unclear. In this work, the electron injection-incomplete discharge approach to achieve the electron accumulation (EA) degree on the nickel-iron layered double hydroxide (NiFe LDH) is proposed, to reveal the intrinsic contribution of EA ...
April 2, 2024
In this work, 2D ferromagnetic M3GeTe2 (MGT, M = Ni/Fe) nanosheets with rich atomic Te vacancies (2D-MGTv) are demonstrated as efficient OER electrocatalyst via a general mechanical exfoliation strategy. X-ray absorption spectra (XAS) and scanning transmission electron microscope (STEM) results validate the dominant presence of metal-O moieties and rich Te vacancies, respectively. The formed Te vacancies are active for the adsorption of OH* and O* species while the metal-O moieties promote the O...
January 12, 2024
Designing high-efficiency and freestanding electrocatalysts hold immense importance in addressing the limitations of powdered electrocatalysts and accelerating the sluggish kinetics of the oxygen evolution reaction (OER) in advancing energy technologies. While dealloyed amorphous ribbons have been shown to be active and self-supporting electrocatalysts toward OER, the underlying enhancement mechanism remains unclear. Here, we developed a dealloyed Ni-Fe-B-Si-P amorphous electrocatalysts with a m...
December 18, 2023
Anodes for the electrolytic splitting of water are usually iridium-based materials. In order to increase the stability of the iridium catalyst, a team at HZB and a group at HI-ERN have now produce ...
November 21, 2023
The continuous oxidation and leachability of active sites in Ru-based catalysts hinder practical application in proton-exchange membrane water electrolyzers (PEMWE). Herein, robust inter-doped tungstenโruthenium oxide heterostructures [(RuโW)Ox] fabricated by sequential rapid oxidation and metal thermomigration processes are proposed to enhance the activity and stability of acidic oxygen evolution reaction (OER). The introduction of high-valent W species induces the valence oscillation of th...
November 15, 2023
Heraeus and Sibanye-Stillwater have developed a pivotal innovation in electrocatalysts for hydrogen production: a new and stable ruthenium-based catalyst for
October 19, 2023
Zinc-air batteries have been under investigation for many years. Despite substantial research efforts, their commercialization has not significantly progressed.
September 13, 2023
Oxygen defects play a critical role in the electrocatalytic oxygen evolution reaction (OER). Therefore, in-depth understanding the structure-activity-mechanism relationship of these defects is the key to design efficient OER electrocatalysts. This relationship needs to be understood dynamically due to the potential for irreversible phase transitions during OER. Consequently, significant efforts have been devoted to study the dynamic evolution of oxygen defects to shed light on the OER mechanism....
June 29, 2023
Researchers around the globe are working on developing high-efficiency catalyst options to make it possible to produce green hydrogen more
May 11, 2023
The oxygen evolution reaction (OER) is a critical step for sustainable fuel production through electrochemistry process. Maximizing active sites of nanocatalyst with enhanced intrinsic activity, especially the activation of lattice oxygen, is gradually recognized as the primary incentive. Since the surface reconfiguration to oxyhydroxide is unavoidable for oxygen-activated transition metal oxides, developing a surface termination like oxyhydroxide in oxides is highly desirable. In this work, we ...