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Tihomir Ivanov Ivanchev, 38, has been charged with conspiring to collect information which could be harmful to the 'safety and interest of the state' on behalf of Russia.
Five Bulgarians accused of spying and carrying out surveillance for the Russian state will go on trial next autumn.
Orlin Roussev, a suspected Russian spy living in Great Yarmouh in Norfolk, will go on trial next autumn.
The three men and two women, all from addresses in London and Norfolk, were arrested in February for offences contrary to the Official Secrets Act. The three men and two women were arrested in February.
A group of alleged Russian spies have appeared at the Old Bailey accused of an offence under the Official Secrets Act.