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2D CaCl crystals with +1 calcium ions displaying unexpected metallicity and ferromagnetism


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IMAGE: (a) Schematic drawings of the sample preparation processes. (b) (i) Cryo-EM image of the Ca-Cl crystals in the ultra-thin reduced graphene oxide (rGO) membrane. (ii) Diffraction pattern of a typical.
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Credit: @Science China Press
Calcium ions are presented in rocks, bones, shells, biominerals, geological deposits, ocean sediments, and many other important materials. Calcium ions also play major roles in the retention of carbon dioxide in natural waters, water hardness, signal transduction and tissue generation. As one of the alkaline earth metals, the calcium atom has two valence electrons according to the octet rule. Up to now, the only known valence state of calcium ions under ambient conditions is +2, and the corresponding crystals with calcium ions are insulating. ....

Liang Chen , Xing Liu , Lu Gou , Xpeng Zhang , Yimin Zhao , Jie Jiang , Pengfei Gao , Bingquan Peng , Shengli Zhang , Yinwei Qiu , Haiping Fang , Hongtao Ren , Chungang Duan , Zejun Zhang , Ruobing Yi , Minghong Wu , Shanshan Liang , Lijuan Zhang , Yufeng Zhang , Guosheng Shi , National Natural Science Foundation Of China , Ministry Of Education China , Chinese Academy Of Sciences , National Natural Science Foundation , Chinese Academy , Xiaoling Lei ,