In the era of artificial intelligence and the internet of things, the emergence of flexible MICAtronics, heterostructures made by van der Waals epitaxy on layered mica, has attracted great research interest due to applications in the fields of flexible ferroelectric memory, dielectric capacitors, and others, but less effort has been dedicated to the realization of flexible piezoelectric inorganic films for energy harvesters and sensors. In this work, an all-inorganic transparent Sm-doped Pb(Mg1/3Nb2/3)O3-PbTiO3 (Sm:PMN-PT) film has been successfully grown on Mica substrate via a simple one-ste...