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"NiS2 nanodots on N,S-doped graphene synthesized via interlayer confine" by Xiaofen Dong, Feijiang Chen et al.

Rational design of high-capacity nanosized composites as anode nanomaterials is crucial to boosting electrochemical performances towards large-scale application for lithium- and sodium-ion batteries (LIBs and SIBs). The small sizes and homogeneous dimensional size distributions are achieved typically by either the surface confinement on the underlying supports, or the encapsulation confinement within the precursors (such as metal-organic frameworks). Herein, we report the ultrasmall NiS2 nanodots on reduced graphene oxide (NiS2/N,S-rGO) synthesized via interlayer confinement as anode nanomaterials for LIBs and SIBs. The composite is synthesized by pyrolyzing a host/guest precursor of sodium dodecyl sulfate ion/[NiEDTA]2− anions co-intercalated MgAl-layered double hydroxide LDH host, without additional sulfur source. The host/guest-derived interlayer nanoconfinement enables the composite to integrate the advantageous features: low-content active NiS2 nanodots (11.0 wt%) with a mean si ....

Carbon Based Composite Nanomaterials , Ost Guest Precursor , Interlayer Confinement , Ithium And Sodium Ion Batteries , Is Nanodots 2 ,