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The TBI said Holly Danielle Lunsford, 43, was charged with arson, burglary and vandalism after she was accused of setting fire to a gas station on Tennessee Avenue.
Kenterrius McGuffie, 27, was arrested and TBI said he faces 13 counts of aggravated rape of a child, among several other charges.
Several suspects have been charged in recent thefts of cattle and tractors in McMinn County, along with other livestock thefts.
The McMinn County Sheriff's Office said deputies were notified about a crash at the intersection of County Roads 100 and 110 at around 9 a.m. Monday morning.
Melissa Blair is accused of having sexual relations with male students at McMinn Central High School. She faces 44 charges.