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The Welsh singer, 85, performed her James Bond hit Diamonds Are Forever at the star-studded event, in celebration of the 60th anniversary of the film franchise.
Hosted by Rebel Wilson, the star-studded show peaked with 2.8million and had a 16.1 per cent share of the viewing audience, making it the sixth most watched programme of the night.
Alesha Dixon proved this on Sunday night when she turned heads at the British Vogue and Tiffany & Co party at London's swanky nightspot Annabel's.
The presenter, 34, looked elegant in a green and black dress as she joined red carpet co-host Tom Allen at the BAFTA nominees reception at The Berkeley Hotel in London on Saturday.
The pair gave fans a glimpse at their beauty preparations ahead of the BAFTA awards on Sunday evening.