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Candidates are vying to be the next mayor of Sacramento. Who's funding the top four?

The primary will be held March 5.

United-states , Sacramento , California , America , American , Azzie-youssefi , Josh-wood , Randall-selland , Sotiris-kolokotronis , Richard-pan , Steve-lebastchi , Kevin-mccarty

'Prettiest ghost town' in Amherst eyes retail tenants

Crews working for WS Development this year finished construction on the shells of three buildings and landscaped and paved much of the parking lot on the property. But WS executives

United-states , Massachusetts , Eggertsville , New-york , Florida , America , Northtown-plaza , Doug-gesel , Briant-sciera , Brian-sciera , Brianj-kulpa , Ws-development

Boys & Girls Club of Brattleboro gets new roof, better air

Boys & Girls Club of Brattleboro gets new roof, better air
reformer.com - get the latest breaking news, showbiz & celebrity photos, sport news & rumours, viral videos and top stories from reformer.com Daily Mail and Mail on Sunday newspapers.

Ben-jerry , John-potter , Michelle-simpson , Lisa-ford , S-development , Canaday-family-trust-foundation , Boys-girls-club , Windham-foundation , Agnes-lindsay , Town-manager-john-potter , Girls-club , Dewitt-block

Geminal-atom catalysis for cross-coupling

Single-atom catalysts (SACs) have well-defined active sites, making them of potential interest for organic synthesis1–4. However, the architecture of these mononuclear metal species stabilized on solid supports may not be optimal for catalysing complex molecular transformations owing to restricted spatial environment and electronic quantum states5,6. Here we report a class of heterogeneous geminal-atom catalysts (GACs), which pair single-atom sites in specific coordination and spatial proximity. Regularly separated nitrogen anchoring groups with delocalized π-bonding nature in a polymeric carbon nitride (PCN) host7 permit the coordination of Cu geminal sites with a ground-state separation of about 4 Å at high metal density8. The adaptable coordination of individual Cu sites in GACs enables a cooperative bridge-coupling pathway through dynamic Cu–Cu bonding for diverse C–X (X = C, N, O, S) cross-couplings with a low activation barrier. In situ characterization and quantum-theoretical studies show that such a dynamic process for cross-coupling is triggered by the adsorption of two different reactants at geminal metal sites, rendering homo-coupling unfeasible. These intrinsic advantages of GACs enable the assembly of heterocycles with several coordination sites, sterically congested scaffolds and pharmaceuticals with highly specific and stable activity. Scale-up experiments and translation to continuous flow suggest broad applicability for the manufacturing of fine chemicals. Heterogeneous geminal-atom catalysts, which pair single-atom sites in specific coordination and spatial proximity, offer a new avenue for the sustainable manufacture of fine chemicals.

Faust-akl , Ra-van-bekkum , S-development , Gaussian-inc , International-organization-for-standardization , Suzuki , Rg-development-of-the-colle-salvetti , Organic-synthesis , Transition-metal-catalysts , Catalyzed-cross-coupling-reactions , Van-bekkum , Chemicals-through-heterogeneous-catalysis

Signs of Lack of Empathy in Your Relationship and What You Can Do

Signs of Lack of Empathy in Your Relationship and What You Can Do
goodmenproject.com - get the latest breaking news, showbiz & celebrity photos, sport news & rumours, viral videos and top stories from goodmenproject.com Daily Mail and Mail on Sunday newspapers.

Ronda-freeman , S-development , Good-men-project , Strategic-transactional-communication , Essential-tools , Leaving-narcissistic , Abusive-relationships ,

Station Twelve developer seeks 69% cut in assessment

The Sheridan Drive properties have a combined full-market value of $21.3 million. But the company contends their market value should be slashed by 69%, to $6.6 million, according to its

Mark-berke , Emily-murphy , Martin-polowy , Northtown-plaza , Brianj-kulpa , Daniel-zazzali , Supreme-court , Town-attorney-office , Ws-development-northtown-property-owner , Whole-foods-market , Ws-development , Whole-foods

Editorial: Palm Beach might need reset on rules for renovating landmarked buildings

Some residents say WS Development went too far in demolishing portions of the landmarked Royal Poinciana Playhouse.

West-palm-beach , Florida , United-states , Tampa-bay , Poinciana , Palm-beach , Brittain-damgard , Alexandra-clark , Johnl-volk , Damon-higgins , Avie-glazer , Landmarks-commission

Gridded Fibers' Restricted Melting Strategy for Gas Permeance and Binding Enhancement of the ePTFE/PPS Filter

Gridded Fibers' Restricted Melting Strategy for Gas Permeance and Binding Enhancement of the ePTFE/PPS Filter
acs.org - get the latest breaking news, showbiz & celebrity photos, sport news & rumours, viral videos and top stories from acs.org Daily Mail and Mail on Sunday newspapers.

South-korea , Han , S-development , Singha , Trans-tech-publications-ltd , Materials-research , Express , Advanced-materials-research , Water-process , Supporting-information ,

Luxury Condo Project Coming to Pompano Beach

U.S. Development will construct Salato Residences, a luxury condominium project in Pompano Beach, Fla., in the Miami area.

Florida , United-states , Canada , Canadian , John-farina , Us-development , S-development , Salato-residences , Pompano-beach , Randall-stofft-architects , South-ocean-boulevard

U.S. Development Announces Salato Residences, Ultra-Luxury,

POMPANO BEACH, Fla., March 21, 2023 (GLOBE NEWSWIRE) -- U.S. Development has announced its newest, ultra-luxury development just off the ocean in Pompano...

Miami , Florida , United-states , Fort-lauderdale , Canada , Boca-raton , Delray-beach , Canadian , Atlantic-ocean , John-farina , Thomas-liepman , Us-development