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"Tuning product selectivity and visible-light-driven activity in oxidat" by Supanan Anuchai, Doldet Tantraviwat et al.

BiOCl has shown a promising photocatalytic activity in non-selective oxidation reactions, however its application in selective photocatalytic organic transformations is often limited by the strong oxidizing ability of photogenerated holes along with inefficient visible-light absorption. Herein, we showed that the poor visible-light-harvesting ability and low product selectivity of BiOCl in the selective oxidation of primary amines to corresponding imines can be alleviated by band energy level modification using a solid solution strategy. We combined an efficient visible light absorption performance of BiOI with a strong oxidizing ability of BiOCl to achieve BiOIxCl1−x solid solution catalysts with substantial improvements in imine yield. Among the BiOIxCl1−x catalysts, BiOI0.2Cl0.8 delivers the highest benzylamine conversion of ~84% with a selectivity of ~96% towards the imine, while pure BiOCl shows much lower conversion (~65%) and product selectivity (~81%). Such excellent perfor ....

Bismuth Oxyhalides , Solid Solution , Visible Light ,

CNN Cuomo Prime Time October 8, 2021 05:57:00

People. like that s the only people who can come after asians. like there hasn t been selectivity within minority communities and different types of infighting in communities. and you re going to take that on. and lisa, nobody takes that on the way you do. i know you open up your heart in these things. obviously, this is close to home, being asian yourself. so we re all going to tune in once again and it s good to see you, my friend. thank you so much, chris. keep doing what you do better than anybody else. it s an all new season of this is life with lisa ling. premieres sunday night 10:00 p.m. only on cnn. there s only one lisa ling. you ll see why when you watch. we ll be right back with the hand-off. ....

Hasn T , Lisa Ling , Close To Home , Anybody Else ,

CNN Cuomo Prime Time October 8, 2021 01:55:00

Scapegoating that has existed, that has continued for more than a century. and so we are highlighting that in this episode. and you know, there s been this incredible movement that has arisen in the wake of all of this violence. and the community is galvanized. and the federal government, corporations, schools are considering teaching asian american history. when i grew up, we had no asian american history. and when you don t have any context for people living in this country, it becomes really easy to overlook and even dehumanize them. listen, and we re seeing it now. and it was interesting, in the most recent wave, whenever you heard that a case was of an asian being abused or assaulted and it wasn t done by a white guy, all of a sudden it confused people. like that s the only people who can come after asians. like there hasn t been selectivity within minority communities and different types of infighting in communities. and you re going to take that on. and lisa, nobody takes that ....

Teaching Asian American History , Wasn T , Hasn T ,

MSNBC Deadline White House August 30, 2019 20:13:00

Don t forget, he did not show this empathy until late yesterday when the storm had already left puerto rico. day before yesterday he was tweeting about how corrupt they were and how he was the best thing to happen to puerto rico. if anyone has politicized it, it s him. now that it s moving towards florida, towards mar-a-lago, all of a sudden i m canceling trips. we all know he doesn t like to make foreign trips anyway, and he already canceled his big trip to go and purchase greenland so this is not a big sacrifice on thinks part. but the selectivity of what he s done, i m still remembering what you stated about how he s throwing bounty towels the last time he went to puerto rico. this time he literally attacked the people of puerto rico while they were in the midst of this very storm now and he cut the fema budget about the wall he told us mexico was going to build. jill, he s also got acting ....

Flow Storm , I Don T , Puerto Rico , Mara Lago , All Ofa Sudden , Bounty Towels , Jill Colvin ,