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Aniston and Pitt were married for five years between 2000 and 2005, and the Fight Club actor guest-starred in season 8's 'The One with the Rumor', where he played Rachel's former classmate . Elsewhere in the new interview, the cast noted other memorable cameos including Tom Selleck, Sean Penn, Paul Rudd and Alec Baldwin. Aniston also praised Ben Stiller's appearance as "hysterical" and Reese Witherspoon – who appeared on the show as her on-screen sister Jill Green – as "brilliant". Kudrow added that she was "blown away by so many" of the people who guest-starred on Friends during its run between 1994 and 2004. NBC/NBCU Photo BankGetty Images