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The Ukrainian children were due to fly yesterday from Warsaw to London Heathrow before going on to Scotland, which will be their home until it is possible to return to Dnipro.
Homes for Ukraine aims to match refugees with individuals, charities and other groups who can provide accommodation for at least six months in Britain.
Andrii Zharikov, 30, a senior lecturer at the university's law faculty, said he had given up trying to bring his sister, Anna-Maria Zharikova, 19, and mother, Tetyana Zharikova, 53, to the UK.