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Svetlana Tsymbal, her daughter Alona and granddaughter Sofia reached the Polish capital after attacks on their hometown of Zaporizhzhia forced them to flee earlier this month.
There are fears that the northern Ukrainian city of Chernihiv (pictured), which has been holding out against Russian forces since the early days of the invasion, could become the next Mariupol.
President Volodymyr Zelensky said Russia has been beaten back by the 'powerful blows' of Ukrainian forces, with 16,000 troops killed, as Putin's invasion entered its fifth week.
Britain's small business owners are boosting the fund through their own donations - with the scheme given the tag 'small business, big difference'.
Orlando Bloom, Unicef's goodwill ambassador visited Ukrainian refugees at a centre in Moldova. More than 1.8 million children have been forced to flee the war zone.