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The TV personality, 35, sent temperatures soaring in strapless leather midi-dress as she was supported on her big night by famous friends including Jess Wright and Candice Brown.
In scenes that will air on Tuesday the stunner, 28, showcases her jaw-dropping figure in the frock as she makes her dramatic entrance.
In scenes that will air on Tuesday, the singeltons dine alfresco before the host tasks them to decide which pair is the 'least compatible' - ahead of the next dumping.
They debuted their hot and heavy romance last year.
Even after a third consecutive number one album, the singer-songwriter remains reluctant to take on the role of popstar