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The legendary singer, 77, put on an edgy display in a leather corset top and studded leggings while belting out some of her hit songs.
It's a unique event in which the finest performers of the day come together for one night of family-friendly entertainment with top-tier royals as guests of honour.
Kimberley Walsh, Nadine Coyle and Nicola Roberts partied with Melanie C at Smirnoff's WE DO US Live launch, an inclusive event promoting accessibility in hospitality
Strictly Come Dancing's Layton Williams and Spice Girl Mel C are among the stars helping Smirnoff launch a campaign to help tackle issues around accessibility in hospitality
Mel B has revealed the Spice Girls would all sleep in the same bed while touring the world in their Nineties heyday.