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Luciana outshined her dapper handsome as she arrived into the bash a couple steps in front of Matt, donning a sexy thigh-high split dress.
The Irish star, 47, picked up Best Actor for his role in Oppenheimer and made his way to the stage with lipstick on his nose after Yvonne accidentally smeared it on his face.
The actor was in attendance for the 2024 Golden Globe Awards with the American beauty, before heading to the glitzy after party.
The American actress, 25, stunned in an incredibly low-cut black dress after she hit the red carpet in a vintage Balmain strapless gown earlier in the night.
The actress, who won Best Performance by a Female, took aim at the Love Story singer, 34, backstage when she was asked what it was like to have the superstar cheer on her success.