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The actress, 54, stunned in a dusky pale pink gown as she shared a kiss with the Hollywood star at the glitzy ceremony after enduring an awkward question about her marriage.
The Saltburn actor, 31, appeared worn out from the busy night of festivities as he was seen heading into the afterparty after missing out on a gong at the Golden Globes.
It was a night to remember for the Irish actor, 47, as he scooped the gong for Best Actor in a Motion Picture: Drama for his performance in Christopher Nolan's Oppenheimer.
Kylie Jenner and Timothee Chalamet cemented their status as Hollywood's new A-list power couple when they made their Golden Globes debut on Sunday night.
Katy and Orlando, who got engaged in 2019 and are still yet to wed, first met at the 2016 Golden Globes afterparty.